Decontamination of select infrastructure materials after a radiological incident using a water-based formulation

Publication date: October 2018

Source: Journal of Environmental Radioactivity, Volumes 193–194

Author(s): Jaleh Semmler, Anthony Snaglewski, Arshad Toor, Zahid Khan, Wenxing Kuang, Konstantin Volchek, Pervez Azmi, Vladimir Blinov, Carl Brown

Abstract

This paper summarizes the results of the decontamination of the infrastructure materials concrete, limestone, brick and asphalt contaminated with ⁶⁰Co, ⁸⁵Sr, ¹³⁷Cs and ²⁴¹Am. The paper focuses on the effect of differences in substrate properties and of the pH of the radionuclide solution used for surface contamination on adsorption or ion exchange of the radionuclides and how these factors affect the decontamination effectiveness. A six-component chemical formulation was used and a process effectiveness of up to 76% was obtained depending on the substrate and radionuclide. Asphalt was the easiest material to decontaminate because of its more hydrophobic nature. Concrete and limestone (and to some extent brick) were less effectively decontaminated as their porous surfaces allowed penetration of radionuclides into water-filled pores in the substrate facilitating adsorption or ion exchange and making them difficult to remove. Brick was the most difficult material to decontaminate because the major component of brick is clay which retains most mono- and divalent ions. The removal of ⁶⁰Co, ⁸⁵Sr and ¹³⁷Cs from the surfaces of concrete, limestone and brick increased when the pH of the radionuclide solutions was moderately acidic to neutral compared to when they were highly acidic. The variability in the test results was similar to that observed in other studies using other decontamination methods, attributed to the inhomogeneity of the substrates used and considered representative of real infrastructure materials.

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